王瑞虎

职称 ：二级研究员，博士生导师

电子邮箱：2021022@hebut.edu.cn

教育背景：

1998/09-2004/03，中科院福建物质结构研究所，博士

2002/05-2003/02，香港理工大学应用生物和化学技术系，联培博士

1994/09-1998/07，曲阜师范大学化学与材料学院，学士···

工作履历：

2021/04–至今，   河北工业大学化工学院，研究员

2008/09-2021/03，中科院福建物质结构研究所，研究员

2007/09-2008/09，美国爱达荷大学化学系，博士后

2006/09-2007/09，美国堪萨斯大学绿色催化中心，博士后

2004/09-2006/09，美国爱达荷大学化学系，博士后

学术任职：

1. 河北工业大学学术委员会委员

2. 河北工业大学学位委员会委员

3. 河北工业大学学位能源催化材料团队负责人

4. 《中国结构化学》编委

5. 《河北工业大学学报》编委

6. 福建省清洁能源材料重点实验室学术委员会委员

研究领域与承担项目：

研究领域：从事二氧化碳催化转化、污染物检测分离、能量存储和转化等研究

基金和项目：

1. 国家自然科学基金面上项目，2020-2023，以氮气光催化合成氨为导向的共价有机框架构筑，主持。

2. 国家自然科学基金面上项目，2017-2020，多孔有机聚合物负载孔内和表面金属纳米粒子的可控合成和催化，主持。

3. 国家自然科学基金面上项目，2015-2018，以水中偶联反应为导向的多孔有机离子框架材料的构筑，主持。

4. 科技部973重大研究计划子课题，2013-2017，半封闭空间机动车排放污染物常温治理的关键纳米技术，主持。

5. 国家自然科学基金面上项目，2013-2016，用于水中芳基氯偶联反应的钯纳米催化剂构效关系，主持。

6. 国家重大科学问题导向项目，2011-2015，铂高效利用与替代的纳米催化剂，主持。

7. 科技部973重大研究计划子课题，2010-2014，纳米材料与技术在水中污染物选择性消除中的应用基础研究，主持。

8. 国家自然科学基金面上项目，2010-2012，绿色高氮杂环含能配合物的合成和性能研究，主持。

奖励与荣誉：

概述：入选中科院百人计划、福建省高层次创业创新、中科院海西研究院卢嘉锡杰出人才计划、河北工业大学元光学者领军B岗。获福建省科技进步一等奖、卢嘉锡优秀导师奖、河北省大学生化学实验创新设计竞赛特等奖指导教师等。

代表性著作：

[1] Shuailong Yang, Haowei Lv, Hong Zhong, Daqiang Yuan, Xinchen Wang and Ruihu Wang*, Transformation of Covalent Organic Frameworks from N-Acylhydrazone to Oxadiazole Linkages for Smooth Electron Transfer in Photocatalysis, Angew. Chem. Int. Ed. 2022, 61, e202115655.

[2] Lei Zou, Rongjian Sa, Hong Zhong, Haowei Lv, Xinchen Wang and Ruihu Wang*, Photoelectron Transfer Mediated by the Interfacial Electron Effects for Boosting Visible-Light-Driven CO₂ Reduction, ACS Catal. 2022, 12, 3550-3557.

[3] Shuailong Yang, Rongjian Sa, Hong Zhong, Haowei Lv, Daqiang Yuan and Ruihu Wang*, Microenvironments Enabled by Covalent Organic Framework Linkages for Modulating Active Metal Species in Photocatalytic CO₂ Reduction, Adv. Funct. Mater. 2022, 32, 2110694.

[4] Bo Cheng, Ke Kong, Linjie Zhang,* Rongjian Sa, Tengteng Gu, Yuan Rui and Ruihu Wang,* Accelerating water oxidation kinetics via synergistic in-layer modification and interlayer reconstruction over hetero-epitaxial Fe-Mn-O nanosheets, Chem. Eng. J. 2022, 441, 136122.

[5] Ke Kong, Bo Cheng, Jun Liang, Yong Guo,* Ruihu Wang,* The aminated covalent organic polymers for reversible removal of concurrent perfluorooctane sulfonate and dichromate, Chem. Eng. J., 2022, 446, 137343.

[6] Zhonglin Li, Pengyue Li, Xueping Meng, Zhang Lin and Ruihu Wang*, The Interfacial Electronic Engineering in Binary Sulfiphilic Cobalt Boride Heterostructure Nanosheets for Upgrading Energy Density and Longevity of Lithium-Sulfur Batteries, Adv. Mater. 2021, 33, 2102338.

[7] Linjie Zhang, Tengteng Gu, KangLong Lu, Liujiang Zhou*, Dongsheng Li and Ruihu Wang*, Engineering Synergistic Edge-N Dipole in Metal-Free Carbon Nanoflakes toward the Intensified Oxygen Reduction Electrocatalysis, Adv. Funct. Mater. 2021, 31, 2103187.

[8] Tengteng Gu, Rongjian Sa, Linjie Zhang, Dongsheng Li and Ruihu Wang*, Engineering Interfacial Coupling between Mo₂C Nanosheets and Co@NC Polyhedron for Boosting Electrocatalytic Water Splitting and Zinc-Air Batteries, Applied Catal. B: Environ. 2021, 296, 120360.

[9] Xing Zhang, Rongjian Sa, Feng Zhou, Yuan Rui, Ruixia Liu, Zhenhai Wen and Ruihu Wang*, Metal-Organic Framework-Derived CuS Nanocages for Selective CO₂ Electroreduction to Formate, CCS Chem. 2021, 3, 199-207.

[10] Jinqing Chen, Hong Zhong, Haowei Lv, Ruixia Liu and Ruihu Wang*, Regulating Utilization Efficiency of the Photogenerated Charge Carriers by Constructing Donor–π–Acceptor Polymers for Upgrading Photocatalytic CO₂ Reduction, ChemSusChem 2021, 14, 2749-2756.

[11] Hong Zhong, Guodong Wu, Zhihua Fu, Haowei Lv, Gang Xu* and Ruihu Wang*, Flexible Porous Organic Polymer Membranes for Protonic Field Effect Transistors, Adv. Mater. 2020, 32, 2000730.

[12] Hong Zhong, Haowei Lv, Shuailong Yang, Daqiang Yuan, Xinchen Wang and Ruihu Wang*, Covalent Organic Framework Hosting Metalloporphyrin-Based Carbon Dots for Visible-Light-Driven Selective CO₂ Reduction, Adv. Funct. Mater. 2020, 30, 2002654.

[13] Zhubing Xiao, Zhonglin Li, Pengyue Li, Xueping Meng and Ruihu Wang*, Ultrahigh volumetric capacity enabled by dynamic evolutions of host-guest pairs in self-supporting lithium-sulfur batteries, Nano Energy 2020, 70, 104522.

[14] Xing Zhang, Rongjian Sa, Shuai Yang, Feng Zhou, Zheng Jiang,* Ruihu Wang*, A non-carbon catalyst support upgrades the intrinsic activity of ruthenium for hydrogen evolution electrocatalysis via strong interfacial electronic effects, Nano Energy 2020, 75, 104981.

[15] Feng Zhou, Rongjian Sa, Xing Zhang, Shen Zhang and Ruihu Wang*, Robust Ruthenium Diphosphide Nanoparticles for pH-Universal Hydrogen Evolution Reaction with Platinum-like Activity, Applied Catal. B: Environ. 2020, 274, 119092.

[16] Zhonglin Li, Zhubing Xiao, Pengyue Li, Xueping Meng and Ruihu Wang*, Enhanced Chemisorption and Catalytic Effects toward Polysulfides by Delicate Modulation of Hollow Nanoarchitectures for Long-Life Lithium-Sulfur Batteries, Small 2020, 16, 1906114.

[17] Haowei Lv, Rongjian Sa, Pengyue Li, Daqiang Yuan, Xinchen Wang and Ruihu Wang*, Metalloporphyrin-Based Covalent Organic Frameworks Composed of the Electron Donor-Acceptor Dyads for Visible-Light-Driven Selective CO₂ Reduction, Sci. China Chem. 2020, 63, 1289-1294.

[18] Feng Zhou, Xing Zhang, Rongjian Sa, Shen Zhang, Zhenhai Wen and Ruihu Wang*, The Promoting Roles of MoS₂ in Electrochemical Overall Water Splitting Promised by Coupled Nickel-Iron (Oxy)hydride/Molybdenum Sulfide/Graphene Composite, Chem. Eng. J. 2020, 397, 125454.

[19] Caiyan Cui, Rongjian Sa, Zixiao Hong,* Hong Zhong and Ruihu Wang*, Ionic Liquid-Modified Click-Based Porous Organic Polymers for Controlling Capture and Catalytic Conversion of CO₂, ChemSusChem 2020, 13, 180-187.

[20] Hong Zhong, Jinwei Gao, Rongjian Sa,* Shuailong Yang, Zhicheng Wu and Ruihu Wang*, Carbon Dioxide Conversion Upgraded by Host-guest Cooperation between Nitrogen-Rich Covalent Organic Framework and Imidazolium-Based Ionic Polymer, ChemSusChem 2020, 13, 6323-6329.

[21] Lei Zou, Rongjian Sa,* Haowei Lv, Hong Zhong and Ruihu Wang*, Recent Advances on Metalloporphyrin-Based Materials for Visible-Light-Driven CO₂ Reduction, ChemSusChem 2020, 13, 6124-6140.

[22] Hong Zhong, Can Yang, Lizhou Fan, Zhihua Fu, Xue Yang, Xinchen Wang and Ruihu Wang*, Dyadic Promotion of Photocatalytic Aerobic Oxidation via the Mott-Schottky Effect Enabled by Nitrogen-Doped Carbon from Imidazolium-based Ionic Polymer, Energy Environ. Sci. 2019, 12, 418-426.

[23] Zhibin Cheng, Hui Pan, Jinqing Chen, Xueping Meng and Ruihu Wang*, Separator Modified by Cobalt-Embedded Carbon Nanosheets Enabling Chemisorption and Catalytic Effect of Polysulfides for High-Energy-Density Lithium-Sulfur Batteries, Adv. Energy Mater. 2019, 9, 1901609.

[24] Zhonglin Li, Zhubing Xiao, Shiqing Wang, Zhibin Cheng, Pengyue Li and Ruihu Wang*, Engineered Interfusion of Hollow Nitrogen-Doped Carbon Nanospheres for Promoting Electrochemical Behaviors and Energy Densities of Lithium-Sulfur Batteries, Adv. Funct. Mater. 2019, 29, 1902322.

[25] Xing Zhang, Feng Zhou, Shen Zhang, Yongye Liang* and Ruihu Wang*, Engineering MoS₂ Basal Planes for Hydrogen Evolution via Synergistic Ruthenium Doping and Nanocarbon Hybridization, Adv. Sci. 2019, 6, 1900090.

[26] Zhubing Xiao, Zhonglin Li, Pengyue Li, Xueping Meng and Ruihu Wang*, Ultrafine Ti₃C₂ MXene Nanodots-Interspersed Nanosheet for High-Energy-Density Lithium-Sulfur Batteries, ACS Nano, 2019, 13, 3608-3617.

[27] Zhubing Xiao, Zhi Yang*, Zhonglin Li, Pengyue Li and Ruihu Wang*, Synchronous Gains of Areal and Volumetric Capacities in Lithium-Sulfur Batteries Promised by Flower-Like Porous Ti₃C₂T_x Matrix, ACS Nano, 2019, 13, 3404-3412.

[28] Yangsen Xu, Xin He, Hong Zhong, David J. Singh, Lijun Zhang* and Ruihu Wang*, Solid Salt Confinement Effect: An Effective Strategy to Fabricate High Crystalline Polymer Carbon Nitride for Enhanced Photocatalytic Hydrogen Evolution, Applied Catal. B: Environ. 2019, 246, 349-355.

[29] Hong Zhong, Zixiao Hong, Can Yang, Liuyi Li, Yangsen Xu, Xinchen Wang and Ruihu Wang*, A Covalent Triazine-based Framework Consisting of Donor-Acceptor Dyads for Visible-Light-Driven Photocatalytic CO₂ Reduction, ChemSusChem 2019, 12, 4493-4499.

[30] Zhubing Xiao, Zhonglin Li, Xueping Meng and Ruihu Wang*, MXene-Engineered Lithium-Sulfur Batteries, J. Mater. Chem. A 2019, 7, 22730-22743.

[31] Dejian Chen, Caiyan Cui, Na Tong, Haifeng Zhou, Xinchen Wang and Ruihu Wang*, Water-Soluble and Low-Toxic Ionic Polymer Dots as Invisible Security Ink for MultiStage Information Encryption, ACS Appl. Mater. Interfaces 2019, 11, 1480-1486.

[32] Hui Pan, Zhibin Cheng, Hong Zhong, Ruihu Wang and Xiaoju Li*, Flexible Cathode Materials Enabled by a Multifunctional Covalent Organic Gel for Lithium-Sulfur Batteries with High Areal Capacities, ACS Appl. Mater. Interfaces 2019, 11, 8032-8039.

[33] Muhammad Asad Ziaee, Yujiao Tang, Hong Zhong, Dongxu Tian* and Ruihu Wang*, Urea-Functionalized Imidazolium-Based Ionic Polymer for Chemical Conversion of CO₂ into Organic Carbonates, ACS Sustainable Chem. Eng. 2019, 7, 2380-2387.

[34] Zhibin Cheng, Zhubing Xiao*, Hui Pan, Shiqing Wang and Ruihu Wang*, Elastic Sandwich-Type rGO-VS₂/S Composites with High Tap Density: Structural and Chemical Cooperativity Enabling Lithium-Sulfur Batteries with High Energy Density, Adv. Energy Mater. 2018, 8, 1702337 (Back Cover).

[35] Zhubing Xiao, Liuyi Li, Yujiao Tang, Zhibin Cheng, Hui Pan, Dongxu Tian and Ruihu Wang*, Covalent Organic Frameworks with Lithiophilic and Sulfiphilic Dual Linkages for Cooperative Affinity to Polysulfides in Lithium-Sulfur Batteries, Energy Storage Mater. 2018, 12, 252-259.

[36] Zhibin Cheng, Hui Pan, Hong Zhong, Zhubing Xiao, Xiaoju Li* and Ruihu Wang*, Porous Organic Polymers for Polysulfides Trapping in Lithium-Sulfur Batteries, Adv. Funct. Mater. 2018, 28, 1707597.

[37] Xing Zhang, Feng Zhou, Weiying Pan, Yongye Liang* and Ruihu Wang*, General Construction of Molybdenum-based Nanowire Arrays for pH-Universal Hydrogen Evolution Electrocatalysis, Adv. Funct. Mater. 2018, 28, 1804600.

[38] Xing Zhang, Xiaolu Yu, Linjie Zhang, Feng Zhou, Yongye Liang* and Ruihu Wang*, Molybdenum Phosphide/Carbon Nanotube Hybrids as pH-Universal Electrocatalysts for Hydrogen Evolution Reaction, Adv. Funct. Mater. 2018, 28, 1706523.

[39] Hong Zhong, Yangxin Wang, Caiyan Cui, Feng Zhou, Shuangqi Hu and Ruihu Wang*, Facile Fabrication of Cu-based Alloy Nanoparticles Encapsulated within Hollow Octahedral N-doped Porous Carbon for Selective Oxidation of Hydrocarbons, Chem. Sci., 2018, 9, 8703-8710.

[40] Zhibin Cheng, Hui Pan, Zhubing Xiao, Dejian Chen, Xiaoju Li* and Ruihu Wang*, Electrostatic Trapping of Polysulfides Enabled by Imidazolium-Based Ionic Polymers for High-Energy-Density Lithium-Sulfur Batteries, J. Mater. Chem. A 2018, 6, 7375-7381.

[41] Linjie Zhang, Taoqing Mi, Muhammad Asad Ziaee, Linfeng Liang and Ruihu Wang*, Hollow POM@MOF Hybrids-Derived Porous Co₃O₄/CoMoO₄ Nanocages for Enhanced Electrocatalytic Water Oxidation, J. Mater. Chem. A, 2018, 6, 1639-1647.

[42] Linjie Zhang, Yanmei Yang, Muhammad Asad Ziaee, Kanglong Lu and Ruihu Wang*, Nanohybrid of Carbon Quantum Dots/Molybdenum Phosphide Nanoparticle for Efficient Electrochemical Hydrogen Evolution in Alkaline Medium, ACS Appl. Mater. Interfaces, 2018, 10, 9460-9467.

[43] Yaqiong Gong, Hong Zhong, Wenhui Liu, Bingbing Zhang, Shuangqi Hu* and Ruihu Wang*, General Synthetic Route toward Highly Dispersed Ultrafine Pd-Au Alloy Nanoparticles Enabled by Imidazolium-based Organic Polymers, ACS Appl. Mater. Interfaces, 2018, 10, 776-786.

[44] Muhammad Asad Ziaee, Hong Zhong, Caiyan Cui and Ruihu Wang*, Additive-Free Hydrogen Generation from Formic Acid Boosted by Amine-Functionalized Imidazolium-Based Ionic Polymers, ACS Sustainable Chem. Eng. 2018, 6, 10421-10428.

[45] Hui Pan, Zhibin Cheng, Zhubing Xiao, Xiaoju Li* and Ruihu Wang*, The Fusion of Imidazolium-based Ionic Polymer and Carbon Nanotubes: One Type of New Heteroatom-doped Carbon Precursors for High-performance Lithium-sulfur Batteries, Adv. Funct. Mater. 2017, 27, 1703936.

[46] Hong Zhong, Zhihua Fu, Jared M. Taylor, Gang Xu* and Ruihu Wang*, Inorganic Acid-Impregnated Covalent Organic Gels as High-Performance Proton-Conductive Materials at Subzero Temperatures, Adv. Funct. Mater. 2017, 27, 1701465.

[47] Zhubing Xiao, Zhi Yang*, Linjie Zhang, Hui Pan and Ruihu Wang*, Sandwich-Type NbS₂@S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate and Long-Life Lithium-Sulfur Batteries, ACS Nano 2017. 11, 8488-8498.

[48] Xiuyun Wang, Yi Liu, Tianhua Zhang, Yongjin Luo*, Zhixin Lan, Kai Zhang, Jiachang Zuo, Lilong Jiang* and Ruihu Wang*, Geometrical-Site-Dependent Catalytic Activity of Ordered Mesoporous Co-Based Spinel for Benzene Oxidation: In Situ DRIFTS Study Coupled with Raman and XAFS Spectroscopy, ACS Catal. 2017, 7, 1626-1636.

[49] Liuyi Li, Lu Li, Caiyan Cui, Hongjun Fan* and Ruihu Wang*, Hierarchical Hollow Covalent Organic Framework-derived Heteroatom-doped Carbon Spheres for Metal-free Catalysis, ChemSusChem, 2017, 10, 4921-4926.

[50] Hong Zhong, Yanqing Su, Xingwei Chen, Xiaoju Li* and Ruihu Wang*, Imidazolium- and Triazine-based Porous Organic Polymers for Heterogeneous Catalytic Conversion of CO₂ into Cyclic Carbonates, ChemSusChem, 2017, 10, 4855-4863.

[51] Zhubing Xiao, Zhi Yang*, Liujiang Zhou, Linjie Zhang and Ruihu Wang*, Highly Conductive Porous Transition Metal Dichalcogenides via Water Steam Etching for High-Performance Lithium-Sulfur Batteries, ACS Appl. Mater. Interfaces, 2017, 9, 18845-18855.

[52] Hong Zhong, Yanqing Su, Caiyan Cui, Feng Zhou, Xiaoju Li* and Ruihu Wang*, Palladium Nanoparticles Supported by Carboxylate-functionalized Porous Organic Polymers for Additive-free Hydrogen Generation from Formic Acid, ACS Sustainable Chem. Eng. 2017, 5, 8061-8069.

专利申请与授权情况：

[1]一种含恶二唑连接基元的共价有机框架材料，王瑞虎，杨帅龙，梁均, 申请号：ZL202111619981.4，公开号：CN114085388B授权日期2022.12.16。